Organic–inorganic heterostructures with programmable electronic properties

Researchers from the University of Strasbourg & CNRS (France), in collaboration with the University of Mons (Belgium), the Max Planck Institute for Polymer Research (Germany) and the Technische Universität Dresden (Germany), have devised a novel supramolecular strategy to introduce tunable 1D periodic potentials upon self-assembly of ad hoc organic building blocks on graphene, opening the way to the realization of hybrid organic–inorganic multilayer materials with unique electronic and optical properties. These results have been published in Nature Communications.

Vertical stacks of different two-dimensional (2D) crystals, such as graphene, boron nitride, etc., held together by weak van der Waals forces are commonly referred to as "van der Waals heterostructures". Such sophisticated multilayer structures can be used as a versatile platform for the investigation of various phenomena at the nanoscale. In particular, mechanical superimposition of the 2D crystals generates 2D periodic potentials which impart to system unconventional physical and chemical properties.

Here a team of European researchers applied a supramolecular approach to form self-assembled organic molecular lattices with a controlled geometry and atomic precision on top of graphene, inducing 1D periodic potentials in the resulting organic-inorganic hybrid heterostructures. For that purpose, molecular building blocks were carefully designed and synthesized. Those are equipped with (i) a long aliphatic tail, directing the self-assembly and the periodicity of the potential, and (ii) a photoreactive diazirine head group, whose dipole moment modulates the surface potential of the underlying graphene sheet. Upon irradiation with ultraviolet (UV) light before deposition on graphene, the diazirine moiety is cleaved and a reactive carbene species is formed. The latter is prone to react with solvent molecules, leading to a mixture of new compounds bearing different functionalities.

The full article can be found here.